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2-methylhexane 2-methylpentane 3-dimethylpentane azeo azeotrope boundaries azeotrope line Bancroft point binary mixtures Carbon Tetrafluoride Chapter constant pressure critical endpoints critical solution temperatures density diagram—Type double azeotrope equilibrium experimental P-T phase fluorocarbon gas-liquid critical line gas-liquid critical point gas-liquid critical temperatures Gibbs free energy given by Eq given in Fig Helmholtz free energy high pressures high-temperature hydrocarbon III-l immiscibility intersection LCST LCST's limited miscibility liquid phases liquid-liquid low-temperature metastable methane miscibility mixture tube molar volume mole fraction n-heptane negative azeotropy P-T phase diagrams phase behavior phase diagram--Type phase diagrams Class phase line plotted positive azeotropy Pr-T Pr-Tr phase Pr–Tr phase diagram pure components quadruple point Regions II-A Rowlinson Schematic experimental P-T shown in Fig solid boundary stopcock temperature and pressure thermodynamic thermopile three-phase line Tr-x diagrams Tr-x phase Type I-A U C E P UCEP UCEP G-L UCST UCST's values vapor pressure curve volume Waals equation