Organosilicon Chemistry: Novel Approaches and ReactionsTamejiro Hiyama, Martin Oestreich Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry. |
Contents
| 1 | |
Chapter 2 SiH Bond Activation by MainGroup Lewis Acids | 33 |
Chapter 3 SiH Bond Activation by TransitionMetal Lewis Acids | 87 |
Chapter 4 MetalLigand Cooperative SiH Bond Activation | 115 |
Chapter 5 Cationic SiliconBased Lewis Acids in Catalysis | 131 |
Chapter 6 TransitionMetalCatalyzed CH Bond Silylation | 171 |
Chapter 7 TransitionMetalFree Catalytic CH Bond Silylation | 213 |
Chapter 8 SilylHeck SilylNegishi and Related Reactions | 241 |
Chapter 10 Lewis Base Activation of Silicon Lewis Acids | 333 |
Chapter 11 Hydrosilylation Catalyzed by Base Metals | 417 |
Chapter 12 Silylenes as Ligands in Catalysis | 439 |
Chapter 13 Enantioselective Synthesis of Silyl Ethers Through Catalytic SiO Bond Formation | 459 |
Chapter 14 Chiral Silicon Molecules | 495 |
| 533 | |
EULA | 551 |
Chapter 9 TransitionMetalCatalyzed Crosscoupling of Organosilicon Compounds | 271 |
Other editions - View all
Organosilicon Chemistry: Novel Approaches and Reactions Tamejiro Hiyama,Martin Oestreich Limited preview - 2020 |
Organosilicon Chemistry: Novel Approaches and Reactions Tamejiro Hiyama,Martin Oestreich Limited preview - 2019 |
Organosilicon Chemistry: Novel Approaches and Reactions Tamejiro Hiyama,Martin Oestreich No preview available - 2019 |
Common terms and phrases
activation addition afford alcohols aldehydes aldol alkenes alkyl alkynes allylation amines Angew applicable aromatic aryl asymmetric bond C–H silylation carbon carbonyl catalyst cation Chem chemistry chiral complex compounds conv coordination corresponding coupling coworkers cross-coupling Denmark derivatives developed direct effective efficient electrophilic enantioselective entry equiv et al ethers example Figure formation functional give highly hydride hydrogen hydrosilanes hydrosilylation imines intermediate involving ketones kinetic kinetic resolution leading Lett Lewis acid Lewis base ligand mechanism mechanistic method molecules nucleophilic observed obtained Oestreich Organometallics oxidative Ph Ph phosphine prepared presence promoted proposed reaction reactivity reagents recently reduction Scheme secondary selectivity showed shown Si─H bond silane silicon silylation SiMe3 species step stereoselective steric studies substitution substrate synthesis Table Tetrahedron tion Toluene transfer transformation yield