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SOME THEORETICAL CONSIDERATIONS
Potential Differences Across Interphases
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adsorbed adsorbed intermediates adsorption anodic anodic and cathodic applied battery benzene bubbling bulk calculated capacitance capacitor capillary charge transfer Chem chemical concentration corresponding corrosion counter electrode coverage current density current/potential curve cyclic voltammetry decrease depends determine drop Electrical Setup electrocapillary electrochemical reaction Electrochemistry electrode reactions electrode surface Electrodes and Electrical electrolyte electrosorption equation H equilibrium exchange current density experiment experimental faradaic free energy fuel cells galvanostatic Gileadi given Helmholtz hydrogen-evolution reaction input interphase ionic ions isotherm kinetic parameters measured mercury metal method obtained operational amplifier oscilloscope overpotential oxidation oxygen oxygen evolution passive phase platinum plot polarization potential difference potential of zero potentiostat pretreatment reactant reaction order reaction takes place reference electrode region resistor reversible potential shown in Fig solvent species steady-state step sweep rate Tafel slope transient Treatment of Results voltammogram Vout water molecules zero charge