Thermoelectricity: Science and Engineering |
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Contents
Introduction By R R Heikes and R W Ure | 1 |
Classical and Irreversible Thermodynamic Treatment of Ther | 7 |
Theoretical Calculation of Device Performance By R W Ure | 15 |
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alloy assumed atoms calculated carrier concentration charge carriers Chem coefficient of performance cold junction compounds conduction band considered constant contact resistance couple crystal decrease defects density determined device diffusion dislocation donor doping effective mass efficiency electrical conductivity electrical resistivity electrons energy gap entropy equation Fermi energy Fermi level figure of merit flux freezing function germanium given by Eq growth heat flow heater high temperatures hole increase interface ionized impurity scattering ions Joule heat lattice thermal conductivity layer liquid maximum measured mechanism melting metal method mixed valence mobility multivalley n-type obtained oxides oxygen parameter particle PbTe Peltier phase diagram phonon Phys potential produced properties radiation ratio result sample Seebeck coefficient semiconductors shown in Fig solid solute specimen stoichiometry surface temperature dependence temperature difference temperature gradient theory thermal conductivity thermocouple thermoelectric materials tion vacancies valence band velocity voltage zero