The Chemistry of Vanadium |
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Page 545
... known to have Dз symmetry . The electronic spectra and temperature - range magnetism of the V2Cl93 - ion has been studied 198 , 202 ; there is appreciable metal - metal interaction within the dimeric anion . A number of halo - aquo ...
... known to have Dз symmetry . The electronic spectra and temperature - range magnetism of the V2Cl93 - ion has been studied 198 , 202 ; there is appreciable metal - metal interaction within the dimeric anion . A number of halo - aquo ...
Page 547
... known copper acetate hydrate dimer . Complexes with Multidentate Ligands Two triarsines , methylbis ( o - dimethylarsino - phenyl ) arsine ( abbreviated o - TAS ) and tris - 1,1,1 - dimethylarsinomethyl ) ethane ( v - TAS ) , are known ...
... known copper acetate hydrate dimer . Complexes with Multidentate Ligands Two triarsines , methylbis ( o - dimethylarsino - phenyl ) arsine ( abbreviated o - TAS ) and tris - 1,1,1 - dimethylarsinomethyl ) ethane ( v - TAS ) , are known ...
Page 586
... known . The latter , prepared by the reaction between dichlorine monoxide and TaCls in carbon tetrachloride , is analogous to Pa2O3C14 98 . Little is known about the chemistry of these oxyhalides , but it is interesting to note that the ...
... known . The latter , prepared by the reaction between dichlorine monoxide and TaCls in carbon tetrachloride , is analogous to Pa2O3C14 98 . Little is known about the chemistry of these oxyhalides , but it is interesting to note that the ...
Contents
Preface | 489 |
Compounds | 497 |
Niobium and Tantalum by D Brown | 553 |
Copyright | |
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acid solution Acta Chem Acta Cryst alkoxides allgem alloys anhydrous anion anorg bromine Brown carbide carbon Chem chemistry chloride cluster compounds cm-¹ complexes compounds coordination CRYSTALLOGRAPHIC DATA crystals cubic diamagnetic dimeric electronic elements fluoride given in Table H. G. von Schnering halides halogen heating Hexagonal hydrofluoric acid hydrogen hydrolysis infrared Inorg known Lattice parameters Less-Common Metals ligands listed in Table magnetic moments melting metal atom molecule Monoclinic NbCls NbOCl3 niobium and tantalum niobium atom niobium pentachloride niobium(V nitride nitrogen octahedral Orthorhombic oxide OXYHALIDES oxytrichloride paramagnetic pentachloride pentafluoride pentahalides pentavalent pentoxide phases Phys prepared properties R. J. H. Clark range of homogeneity reaction reacts reduction Rhombohedral Russ salts Scand Schäfer sodium solid solvents species spectra spectrum stable structure sulphur symmetry TaCls tantalum(V temperature Tetragonal tetrahalides tetrahydrofuran tetravalent thermal decomposition trigonal vanadium atom vanadium tetrachloride vanadium trichloride vanadium(III vapour