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activity coefficients Ag(c aluminosilicates aluminum Ca2+ CaCO3(calcite cadmium calcite calcium calculated carbonate cations Cd2+ CH3COO Chapter chelates Chem chemical CODATA copper Cu2+ DCPD diagram DTPA EDTA effect of redox equilibrium constant Equilibrium Reaction equilibrium relationships estimate Fe(III Fe2+ Fe3+ form in soils gibbsite given by Reactions goethite Hg(l Hg2+ hydrolysis hydrolysis species hydroxyapatite increases ionic strength iron kaolinite line in Fig log Al3+ log SOl log unit magnesium magnetite manganese mercury Mg2+ Mn2+ mole fraction molybdenum Norvell oxides Pb2+ pH range phosphate phosphorus plotted in Fig precipitate pyrolusite Reaction log redox redox range reduced rhodochrosite shift shown in Fig silicates Smith and Martell Soil Sci soil solution soil-Cu soil-Fe soil-Zn solubility solubility line solubility relationships solution species Source Remarks stable strengite sulfate sulfides sulfur Table U.S. Bur unit decrease variscite W. L. Lindsay Wagman zinc Zn2+