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H SOME THEORETICAL CONSIDERATIONS
Evaluation of Kinetic Parameters
22 other sections not shown
adsorbed adsorbed intermediates adsorption anodic anodic and cathodic applied battery benzene bulk calculated capacitance capacitor capillary Chem chemical concentration corr corresponding corrosion counter electrode coverage current density curve cyclic voltammetry decrease depends determined double-layer drop Electrical Setup electrocapillary Electrochemistry electrode reactions electrode surface Electrodes and Electrical electrolyte electrosorption equilibrium exchange-current density experiment experimental faradaic free energy Frumkin fuel cells function of potential galvanostatic given hydrogen hydrogen-evolution reaction input interphase ions isotherm kinetic parameters layer linear measured mercury metal method nitrogen obtained operational amplifier oscilloscope output overall reaction overpotential oxidation oxygen oxygen evolution platinum plot polarization Polarography potential difference potential of zero potentiostat pretreatment pseudocapacity rate-determining step reactant reaction order reaction takes place reference electrode resistance reversible potential shown in Fig solution solvent species specific rate constant steady-state sweep rate Tafel slope transient Treatment of Results voltage water molecules zero charge