Interfacial Electrochemistry: An Experimental Approach |
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Contents
SOME THEORETICAL CONSIDERATIONS | 1 |
Evaluation of Kinetic Parameters | 60 |
Adsorption of Intermediates | 75 |
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activation adsorbed adsorption anodic applied assumed battery bulk calculated capacity cathodic cell charge chemical circuit Compare concentration Consider constant controlled corresponding corrosion coverage current density curve decrease depends determined difference diffusion discussed double double-layer drop effect Electrical electrochemical electrolyte energy equal equation equation II equilibrium experiment experimental field function further given hydrogen important increasing input intermediates interphase ions isotherm kinetic known layer limiting linear measured mechanism mercury metal method molecules Note observed obtained occurs operational amplifier output overpotential oxidation parameter phase platinum plot positive potential potentiostat range reached reactant reaction recorder reference electrode region resistance respect reversible Setup shown in Fig simple solution species step studied surface sweep rate taking place teflon transfer transient Treatment variation voltage zero ᎡᎢ