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ATOMIC STRUCTURE AND SPECTRA
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absorption antibonding antisymmetric applied field approximation atomic orbitals average beam calculation Chapter complex components configuration consider corresponding Coulomb current density degeneracy degenerate depends determined diagram diamagnetic diatomic molecule dipole moment operator direction discussion effect electric dipole transitions electric field energy levels equation evaluated example excited expression force constant frequency g-value give rise ground hamiltonian helium Hint hydrogen atom induced integral intensity interaction ionization potential irreducible representations labelled ligands linear magnetic field magnitude matrix elements mixing modes molecular orbital momenta nucleus observed obtained occur octahedral oscillator overlap p-orbitals parallel paramagnetic paramagnetic current Pauli principle perpendicular photon polarizability polarization potential energy quantum number radiation Raman repulsion resonance result scalar selection rule shielding constant shown in Fig singlet span the irreducible spectra spectrum spherical spin-orbit coupling structure susceptibility symmetry tion transition dipole triplet unperturbed vector potential vibrational vibrational transition wave function write written Z-direction zero