Asymmetric Reactions and Processes in Chemistry: Based on a US-Japan Seminar Cosponsored by the Japan Society for the Promotion of Science and the National Science Foundation and Held at Stanford University, Stanford, California, July 7-11, 1981
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Synthetic Control Leading to Natural Products
Asymmetric Synthesis of Chiral Tertiary Alcohols in High
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acetate acid addition alcohols aldehyde aldol alkyl American Chemical Society amino acid applications approach asymmetric induction asymmetric synthesis bond BPPM carbon carried catalyst chelation Chem Chemistry chiral chiral center chromatography Cited cleavage column complex compounds configuration COOH course derived determination developed diastereomer double effective efficient enantiomer enantiomeric enantiomerically pure enolate enzyme equation erythro ester ether example Figure followed formation gave give highly hydrogenation immobilized interactions intermediate involving Japan ketones kinetic resolution lead ligands Literature lithium material metal method methyl group Mukaiyama natural observed obtained optically active organic prepared present racemic ratio reaction reagents recently reduction relative requires Research resolution ring Scheme selectivity separation shown shows solution solvent specific starting step stereochemistry stereoisomers stereoselectivity steric structure studied substrate sulfoxide synthetic Table Tetrahedron Lett tion transfer University utilization various yield он