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appears applied force approximation assumed average behavior break center of mass chain ends chain segments Chapter computation considered constant copolymer creep crosslinked crystal crystalline curve dashpot decrease dielectric dipole discussed distance effect elastic elongation energy loss entanglements equation equilibrium experimental fact filler free volume freely orienting chain freely orienting segments friction factor function given by Eq glass temperature Hence jump frequency large number length linear liquid load material measurements melting point method modes of motion modulus molecular weight monomer monomer units natural rubber network chains nuclear magnetic resonance obtained plot PMMA polyisobutylene polymer chain polymer molecule Polymer Sci polymerization polymethyl methacrylate polystyrene polyvinyl chloride predicted problem quantity reason region relation response result retardation rotation sample shear rate shown in Figure stress relaxation stress-strain curve stretched superposition principle tear tensile strength term tion variation vibration viscosity zero