Inorganic and Organometallic Reaction Mechanisms"Inorganic and Organometallic Reaction Mechanisms, Second Edition covers both classic inorganic reaction mechanisms and organometallic reaction mechanisms. Introductions are provided for each group of reaction mechanisms, and extensive problems (many with references) are offered at the end of each chapter, as are summaries that provide students with thoughtful overviews." "This book is intended for advanced undergraduate and graduate students and instructors in inorganic and organometallic chemistry. It will also be a useful tutorial for organic chemists who use organometallic reagents for syntheses."--BOOK JACKET.Title Summary field provided by Blackwell North America, Inc. All Rights Reserved |
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Contents
Chemical Kinetics | 1 |
Ligand Substitution Reactions on SquarePlanar | 43 |
Substitution Reactions of Octahedral WernerType | 71 |
Copyright | |
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Common terms and phrases
18-electron activation alkene alkyl American Chemical Society associative attack bond bridging calculated catalyst Chapter Chem clusters complexes concentration considerable considered consistent coordination Copyright dependence determined discussed dissociation effect electron transfer energy Equation evidence examples exchange field first-order formation formed geometry hydride hydrogenation illustrated important increase indicate Inorg intermediate involves isomers J. D. Atwood kcal/mole kinetic leads ligand mechanism mechanistic metal carbonyl metal center metal complexes migration nature nucleophilic observed occurs octahedral organometallic oxidative addition PBuz phosphine plot possible PPhz presented radical rapid rate constant rate law reactivity rearrangement reductive elimination references relative Reprinted with permission resonance scheme shown in Figure shown in Table similar solvent species spectra square square-planar step stereochemistry steric structure studies substitution reactions suggested temperature tetrahedral tion trans undergo
Bibliographic information
| Title | Inorganic and Organometallic Reaction Mechanisms |
| Author | Jim D. Atwood |
| Edition | 2, illustrated |
| Publisher | VCH Publishers, 1997 |
| Original from | the University of Michigan |
| Digitized | Feb 18, 2010 |
| ISBN | 1560819553, 9781560819554 |
| Length | 312 pages |
| Export Citation | BiBTeX EndNote RefMan |