## The theory of vibrational spectroscopy and its application to polymeric materials |

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### Contents

State of the Art in Molecular Spectroscopy | 1 |

Elementary Classical Mechanical Treatment of Molecular | 9 |

The Vibrational Problem in Internal Coordinates | 37 |

Copyright | |

15 other sections not shown

### Common terms and phrases

assignments atoms axis benzene bond Calc calculated frequencies cartesian coordinates cartesian displacement coordinates CCC def CH ipb Chapter character table Chem chemical repeat unit conformation consider crystal crystalline defects defined determined diagonal dipole discussed dispersion curve eigenvectors force constants force field illustrated in Figure infrared and Raman intensities intermolecular forces internal coordinates irreducible representations isolated chain Koenig Krimm lattice line group matrix methylene molecular molecule normal coordinate calculations normal modes observed and calculated observed frequencies obtained parameters permission from ref phase phonon Phys point group polarized polyethylene polymer polymer chain potential energy Potential Energy Distribution Raman active Raman scattering Raman spectra Reprinted by permission rotation Schachtschneider secular equation selection rules shown in Figure spectroscopy stretching structure symmetry coordinates symmetry operations symmetry species torsional translational repeat unit unit cell valence force field values vector vibrational spectroscopy vibrational spectrum Zerbi ZHCC