Models for the Synthesis of Linear Metallic Oligomers: The bis(diorganohalotin) tetracarbonylosmium system. The [[3,3'-(trimethylenedinitrilo)-di-2-butanone dioximato] (1-)] rhodium system. Part I. Part II, Parts 1-2 |
Common terms and phrases
14H total 3,3'-(trimethylenedinitrilo)-di-2-butanone added addition products adduct alkyl halides Amer Anal anion benzene boron bridged bubbled butanone Calcd Caled carbon tetrachloride Chem Co(DO cobalt colorless compounds cyclohexyl dianion dichloride 25 dichloromethane dihydride diiodide 17 dioximato dioximato](1 dioximato](1-)]rhodium electron ethanol excitonic filtered and washed formed Found Hâ‚‚Os hexane hydrogen chloride Inorg KBr pellet ligand mechanism mercuric chloride metal metal bonds methyl MHz in CDC13 mixture was stirred mmol molecule nitrogen nmr 60 MHz nucleophile organotin osmium oxidative addition oxidative addition reactions oxime bridge phenyl planar 27 polymer polymerization precipitate proton Raman reaction mixture reactivity recrystallized recrystallized from dichloromethane Rh(DO rhodium rhodium complex room temperature ruthenium short silica gel silica gel sodium borohydride solid solvent square 27 stereochemistry superconductivity tetracarbonylosmium THF 5 ml tin complexes tin hydrides trans-bis triphenylphosphine triphenyltin chloride unsaturated 27 vacuum warmed to room washed with ether yield