Advances in Organometallic Chemistry, Volume 36This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species that are so reactive that they only have a transient existence at ambient temperatures to those thatare thermally very stable. They are used extensively in the synthesis of useful compounds on both small and large scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advances in organometallic chemistry. In basic research, organometallics have contributed inter alia to:
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Contents
| 57 | |
Chapter 3 Quantification of Steric Effects in Organometallic Chemistry | 95 |
Chapter 4 Organotransition Metallic Chemistry of Sulfur Dioxide Analogs | 159 |
Chapter 5 Silaorganometallic Chemistry on the Basis of Multiple Bonding | 229 |
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Common terms and phrases
adduct afforded alkoxide alkyl American Chemical Society analogous Angew anion bond angles bond distances bond lengths boron bridge hydrogens calculated carbon carbonyl carboranes cation Chem chemistry closo-carboranes cluster co-workers compounds cone angle conformation coordination mode crystal structure cumulene cyclopentadienyl deltahedra derivative diborane dimeric dioxide donor electrophilic energy Engl formation fragment fullerenes geometry Herberhold HMPA hydride iminooxosulfuranes Inorg insertion interaction intermediate intramolecular isomers kinetic lanthanide ligand linear measured metal center methyl mode of coordination Molecular structure molecule nido nitrogen NMe2 observed olefin orbitals organolanthanide Organomet organometallic chemistry Organometallics oxidation phosphine Phys plexes polyboranes polymerization porphyrin PPh3 prepared produce protons reaction reactivity reacts ring Scheme silanediyl silanes silicon atom silylene complexes SiMe3 solid angle species spectroscopic sphere stable steric effects substituents sulfines sulfur diimides synthesis t-Bu tion transition metal Waals X-ray crystal Zybill