## Thermodynamics of Fluids: An Introduction to Equilibrium Theory |

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according activity coefficients adsorbed adsorption applied assume behavior binary calculations Chem chemical close coefficient combining completely components composition considered constant contains correlation corresponding critical curve defined degrees of freedom denotes dependence derived described determined developed deviations differential effects elements energy entropy equal equation equilibrium Error evaluated Example experimental expressed factor Figure fluid follows fraction fugacity function gases Gibbs give given heat ideal ideal-gas independent integral interaction interest internal isothermal known liquid macro methane micro mixing mixture molal mole molecular molecules motion obtained partial phase potential present pressure properties pure quantities range reaction reduced referred represents shows simple solid solution species specified standard substances Substituting Table temperature thermodynamic tion values vapor variables virial coefficient volume