Synthesis, Structure, and Bonding of New Types of Iron and Cobalt Nitrosyl Clusters Containing Tri-, Tetra-, and Pentacoordinated Sulfur And/or Nitrogen Atoms |
Contents
Results and Discussion | 23 |
References and Notes | 41 |
The Synthesis and Structural | 45 |
7 other sections not shown
Common terms and phrases
100 mV/sec cyclic Acta Crystallogr anion antibonding atoms bond angles bond lengths bond order bridging ligands bridging NC CH3)3 calculated structure factors carbon atoms cation CH2Cl2 solution Chem Chemical cm¹ cobalt cobalt atoms completely bonding iron coordinates crystallographic cubane-like distances and bond electron-pair electronic configuration Fe-Fe bonds Fe-Fe distances Fe-S Fe4S4 core Figure Fortran four fragment g/cm³ geometry H. A. Levy hydrogen atoms infrared spectrum Inorg iron atoms J. C. Calabrese Jahn-Teller effect KBr pellet L. F. Dahl lattice constants least-squares least-squares planes least-squares refinement metal cluster molecular molecule monoanion monocation NC CH3)3 ligands nitrosyl stretching nonhydrogen atoms Observed and calculated orthorhombic peak pentacoordinated nitrogen atom Ph.D quadruply bridging NC R. S. Gall R₁ R₂ SSCE sulfur symmetry synthesis t₁ t₂ Table II continued TBAH tetrairon Thesis Appendix Trinh-Toan triply bridging unit cell University of Wisconsin-Madison W. R. Busing Wisconsin-Madison 1972 µ3-NC CH