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Transport equations for concentrated electrolytes
17 other sections not shown
activity coefficient analogous anode approximate assume binary electrolyte boundary conditions boundary layer calculated catex membrane cathode centration channel Chem collocation method concentration gradient considered constant coordinate corresponding current density current density distribution current lines defined denotes dependence derivatives diaphragm difference differential equations diffusion coefficient diffusion equation dimensionless distance elec electric electrochemical electrochemical potentials electrode potential electrode reaction electrode surface electrolyte equal to zero equilibrium error example expressed flux of ions formulae free convection function galvanic cell grid points hence Hull cell inlet inner potential interface introduce ion fluxes iteration Laplace equation linear liquid mass method molal Nernst diffusion layer obtain overpotential parameters plate electrode polarization potential drop potential values Prandtl pressure quantities rate of flow region relation shown in Fig solvent solving the Laplace specific resistance subscript Table temperature term terminal voltage thermodynamic thickness transference number transformation transport viscosity