The Chemistry of the Actinide Elements, Volume 2
Springer Netherlands, Oct 31, 1986 - Science - 912 pages
The first edition of this work appeared almost thirty years ago, when, as we can see in retrospect, the study of the actinide elements was in its first bloom. Although the broad features of the chemistry of the actinide elements were by then quite well delineated, the treatment of the subject in the first edition was of necessity largely descriptive in nature. A detailed understanding of the chemical consequences of the characteristic presence of Sf electrons in most of the members of the actinide series was still for the future, and many of the systematic features of the actinide elements were only dimly apprehended. In the past thirty years all this has changed. The application of new spectroscopic techniques, which came into general use during this period, and new theoretical insights, which came from a better understanding of chemical bonding, inorganic chemistry, and solid state phenomena, were among the important factors that led to a great expansion and maturation in actinide element research and a large number of new and important findings. The first edition consisted of a serial description of the individual actinide elements, with a single chapter devoted to the six heaviest elements (lawrencium, the heaviest actinide, was yet to be discovered). Less than 15 % of the text was devoted to a consideration of the systematics of the actinide elements.
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5f electrons absorption spectrum acid Acta Crystallogr actinide elements actinide ions actinide series alpha Am(in Am(v Am(vi americium anions aqueous solution Asprey atomic number Baybarz behavior berkelium Bk(iv bond calculated californium californium metal Chem chemistry chloride Choppin complexes compounds configuration coordination crystal field cubic curium decay diffraction divalent Edelstein einsteinium elution energy enthalpy fermium fluoride formation Fuger Haire half-life halides hexagonal hydration Inorg ionic ionic radius isotopes Laboratory lanthanide lanthanide and actinide Lett ligands magnetic susceptibility measurements monoclinic neptunium neutron nobelium Nucl nuclear Nugent orthorhombic oxidation oxygen Penneman Peterson phase Phys plutonium potential predicted prepared Proc Radioanal Radiochem Radiokhimiya radius reaction reactor reduction Seaborg separation solvent extraction spectra stability structure studies Symp Table temperature tetragonal tetravalent thermodynamic thorium transition transplutonium elements Transuranium Transuranium Elements trivalent actinides uranium uranocene USAEC Report values x-ray