Thermodynamics and Chemistry, Part 48For undergraduate and graduate-level Chemical Thermodynamics courses in Chemistry, Biochemistry, and Chemical Engineering. This accessible, straightforward treatment of classical thermodynamics focuses on the derivation of the fundamental laws of thermodynamics and other topics of interest to scientists and engineers. Although this book is designed for second courses in thermodynamics, there is nonetheless an intensive discussion of basic topics that is intended to reinforce students' understanding of the material. This text reinforces and extends the knowledge the reader has gained from an earlier exposure to thermodynamics. *Inclusion of topics relevant to chemistry, but often omitted from thermodynamics texts-Helps students to extend the applications of fundamental concepts; gives instructors the option to assign these topics. *Several important pedagogical features-Includes problems at the end of each chapter. *Terms and concepts defined in a clear, rigorous, and understandable manner. *Modern symbols and current nomenclature, such as the notation recommended by the International Union of Pure and Applied Chemistry. *Clear indication of the conditions under which a particular e |
Contents
SOME BASIC PROPERTIES AND THEIR MEASUREMENT | 8 |
THE FIRST LAW | 27 |
THE SECOND AND THIRD LAWS | 64 |
Copyright | |
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Common terms and phrases
activity coefficient Amix amount aqueous ArGm Asol Hm binary calculate calorimeter Carnot engine cell reaction chemical potential closed system cm³ coexisting components composition constituent curve defined electrode electrolyte enthalpy change enthalpy of solution equal equation equilibrated equilibrium constant evaluate experimental expression fluid fugacity function galvanic cell gas phase Gibbs energy given heat capacity Henry's law ideal gas ideal gas mixture ideal-dilute solution independent variables infinite dilution infinitesimal integral intensive properties isothermal liquid mixture measured molality molar entropy molar quantities mole fraction molecules nonelectrolyte number of independent obtain partial derivative partial molar volume partial pressure path phase diagram piston positive pure liquid pure substance Raoult's law relation reversible process shown in Fig solid solubility solvent species spontaneous standard molar enthalpy standard molar reaction temperature and pressure thermal thermodynamic equilibrium total differential transfer vapor zero