In-situ Synthesis of Polymer Nanocomposites
John Wiley & Sons, Oct 5, 2011 - Technology & Engineering - 350 pages
The book series "Polymer Nano-, Micro- and Macrocomposites" provides complete and comprehensive information on all important
aspects of polymer composite research and development, including, but not limited to synthesis, filler modification, modeling, characterization as well as application and commercialization issues. Each book focuses on a particular topic and gives a balanced in-depth overview of the respective subfi eld of polymer composite science and its relation to industrial applications. With the books the readers obtain dedicated resources with information relevant to their research, thereby helping to save time and money.
In-situ intercalative polymerization in the presence of filler provides distinct advantages when compared to other nanocomposite synthesis
techniques including the possibility to polymerize a large range of thermoplastic and thermosetting polymers, improved handling of gaseous
or liquid monomers or high pressure polymerization and improved control of heat of polymerization. This volume aims to highlight these
advantages of the generation of polymer nanocomposites with a large spectrum of polymer matrices. Following an overview of the synthesis
methodologies, the text goes on to discuss the most relevant polymer materials, including polyamides, polyolefi nes, polyacrylates, polyethylenes, polyurethanes, polyesters and polyepoxides.
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acid alkyl ammonium Appl ATRP caprolactam carbon carbon nanotubes catalyst supporting cations cellulose Chem chemical clay layers clay nanocomposites clay surface Cloisite CNTs composites copolymer crosslinking curing CW–PFA decrease degradation diffraction dispersion epoxy exfoliated exfoliated nanocomposites filler function furan graphene hydroxyl improved in-situ polymerization increase initiator inorganic interaction intercalated interface interlayer spacing Macromol Macromolecules materials mechanical properties melt metallocene method modified clay modulus molecular weight molecules monomer montmorillonite morphology MWNT nanoclay nanocomposites nanofillers nanoparticles nanotubes observed organically modified organoclay oxygen P3HT P3HT–MWNT Papaspyrides particles peak permission phase Phys platelets PNCs polyamide polyester polymer chains polymer matrix polymer nanocomposites polymerization activity polymerization technique polyol prepared prepolymer presence PS–MMT nanocomposites PUCNs ratio reaction Reproduced from Ref resin ring-opening polymerization shown in Figure silicate silicate layers smectites solvent spectra styrene surface modification surfactant synthesis tactoids temperature tensile thermal stability Zhang