Carbon-carbon Bond Formation Between Pi-ligands Coordinated to Iron: Thermolysis and Photolysis of (cyclopentadiene)-tricarbonyliron |
Common terms and phrases
1,3-pentadiene 15 mmol acetone acid addition adduct allyl Amer authentic samples benzene benzene-d6 butadiene butadiene and ethylene calcd catalyst system CF3CO2D Chem chloride CO)₂Fe CO₂Me codimerization compounds coordinatively cyclization cyclopentadiene cyclopentene d₁ degassed deuterium content dicarbonyliron dimer dimer dimer 13 distilled double bond eluted endo ester ethanol ether ethylene evaporated exo hydrogen formed gave heated at 100 hexane hexane was photolyzed hydrogen hydrogen transfer intermediate iodide iodo iron complex isolated by preparative isomer isomerization isoprene isoprene tricarbonyliron ligand mass spectrometry Mass spectrum metal hydride methyl acrylate mmol nickel Nmr CC14 nmr tube olefin organometallic oxidation peak phosphine photolysis piperylene ppm error preparative glc column propylene proton ratio reaction resonance rhodium(III room temperature sealed under vacuum sequence solution solvent spectra styrene substituted side T. H. Whitesides tetracarbonyliron thermolysis tion trans tricarbonyl tricarbonyliron triphenylphosphine tube was heated unsaturated vacuum line yield соаме