The Chemistry of Organozinc Compounds: R-Zn

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Zvi Rappoport, Ilan Marek
John Wiley & Sons, Sep 27, 2007 - Science - 1140 pages
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The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects.

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Contents

1 The reaction mechanisms of zinc enzymes
1
2 Structural organozinc chemistry
31
3 Thermochemistry of organozinc compounds
137
4 67Zn NMR a tool for coordination chemistry problems
147
5 Mass spectrometry of organozinc compounds
163
6 Dynamic behavior of organozinc compounds
193
7 Cyclopropanation mediated by zinc organometallics
237
8 Functionalized organozinc compounds
287
12 Enantioselective addition of organozinc compounds
555
13 Rearrangements of organozinc compounds
595
14 11Bismetallated species
641
15 The chemistry of organozincate compounds
685
16 Fluorinated organozinc reagents
713
17 Electrochemical generation and reaction of zinc reagents
755
18 The chemistry of zinc enolates
797
19 Carbozincation of alkenes and alkynes
863

9 Photochemical transformations involving zinc porphyrins and phthalocyanines
395
10 Synthesis and reactions of allenylzinc reagents
421
11 Palladium or nickelcatalyzed crosscoupling reactions with organozincs and related organometals
457
Author index
979
Subject index
1053
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