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Free ions and crystal field theory
Perturbation theory and its applications
The magnetic properties of transition metal ions in cubic crystal fields
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antiferromagnetic applied approach approximation arise assumed atom axially becomes calculation changes Chapter compared complexes components compound configuration considered constant contribution crystal field cubic defined degeneracy degenerate dependent detail determinant diagram diamagnetic discussed distorted effect electron energy levels Equation evaluation example exchange excited experimental expression field terms Figure first-order free ion functions g values given gives ground term hence illustrated increases interaction involves leads ligand magnetic behaviour magnetic field magnetic properties magnetic susceptibility matrix elements measurements mixing molecular molecule negative observed obtained octahedral operator orbital orbital angular momentum paramagnetic parameters particular perturbation positive possible quantum mechanical range reduced reference second-order Zeeman shown single solution spin spin-orbit coupling splitting structure symmetry Table temperature tetragonal tetrahedral theory units values variation of ū wave-functions weak Zeeman coefficients zero