Organic Sulfur Chemistry, Volume 2

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CRC Press, Oct 24, 1991 - Science - 448 pages
This volume contains fundamental knowledge regarding the structure and mechanisms of organic sulfur chemistry. Topics include sulfur bondings, effects of sulfur groups, stereochemistry around sulfur, substitution, ligand coupling within s-sulfurane, oxidation, reduction and rearrangement. References in this work total over 2,300. Anyone with an interest in organic sulfur chemistry will find this book to be fascinating reading.
 

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Contents

Substitution
31
Tricoordinate and Tetracoordinate Sulfur Groups
48
Neighboring Group Effects of Sulfur Groups
59
Chapter 3
67
Tetracoordinate Sulfur Compounds
92
Stereochemistry of oSulfonyl Carbanions
104
Tricoordinate Sulfur Compounds
142
Chapter 6
145
Oxidation and Oxygenation
203
Oxidation of Thiols and Disulfides to Sulfur Species of Higher
216
Oxidation and Oxygenation of Sulfides and Sulfoxides
253
Stereochemistry
275
References
281
Chapter 7
293
IX
296
Reduction of Sulfuric Acid and Sulfate
360

Nucleophilic Substitution on Tetracoordinate Sulfur Atoms Possible
168
Pentacoordinate Sulfur Compounds
174
Chapter 5
183
Ligand Coupling and Pseudorotation
190
Ligand Coupling on Other Atoms
196
VIII
199
The Pummerer Reaction
380
Sigmatropic Rearrangements
400
142b Hayes R A and Martin J C Sulfurane chemistry in Organic Sulfur Chemistry Bernardi F
408
References
414
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