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12-inch ball valve 310 stainless steel ball valve seat Bureau of Mines carbon steel chemical vapor deposition chromium coal gasification pilot coating thickness coatings were produced CVD molybdenum CVD reaction chamber CVD titanium carbonitride CVD titanium nitride D. M. Soboroff Department of Energy DEPOSITION OF WEAR-RESISTANT g/hr gasification pilot plant hardfacings helium hexafluoride to tungsten hydrogen hydrogen-to-nitrogen mole ratio hydrogen-to-tungsten hexafluoride ratios induction heated interagency agreement introduced through calibrated J. B. Stephenson laboratory-scale system Large-Scale CVD Lock hoppers low-Btu coal gasification Metallurgy Research Center methane Morgantown Mounting media nickel foil nickel-plated steel nitride coating produced nitride on low-carbon nitrogen nonadherence obtained for CVD produced on low-carbon reactants reaction temperature Report of investigations resistance Rolla Metallurgy Research shown in figure steel X 500 Stellite 6B substrates by reacting tetrachloride flow rate thermocouples titanium nitride coatings titanium tetrachloride flow tungsten hexafluoride tungsten on nickel-plated typical specimen U.S. Department U.S. Dept WEAR-RESISTANT COATINGS