Vacuum Ultraviolet Photoionization and Photodissociation of Molecules and Clusters
World Scientific, 1991 - Science - 572 pages
This monograph reviews the recent progress in vacuum ultraviolet (VUV) photoionization and photodissociation processes. Photoionization, photoelectron, and fluorescence spectroscopic techniques have played an important role in revealing the photoionization and photodissociation dynamics of molecules in the vacuum ultraviolet region and in providing accurate energetic and spectroscopic information of ions as well as neutral molecules. The book represents the first detailed review of major experimental developments in the studies of single vacuum ultraviolet photon ionization and dissociation processes of gaseous molecules and clusters.
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absorption adiabatic adiabatic ionization ammonia dimer analysis angular distribution Ar2+ atom autoionization bond energies branching ratios calculations channel Chem collection efficiency continuum cross section curve Dehmer detection detector dimer cation dissociation energy electron energy excited experimental experiments false coincidences Figure formation fragment Franck-Condon Franck-Condon factors FWHM geometry hydrogen initio intensity ionic ionization energies ionization potential kcal/mol kinetic energy laser Lett Mass Spectrom mass spectrometry measurements method molecular beam molecular orbital molecules monomer neutral observed obtained orbital peak PEPICO spectrum photoelectron spectroscopy photoelectron spectrum photoionization photon energy Phys PIE spectrum potential energy potential energy surfaces pulsed quantum radicals reaction region rotational Rydberg series shape resonance shown in Fig species spectra spectrometer structure studies synchrotron radiation Taken from Ref technique theoretical threshold Tomoda and Kimura Torr transition vertical ionization energies vibrational levels vibrationally resolved water dimer wavelength
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