Mechanical Catalysis: Methods of Enzymatic, Homogeneous, and Heterogeneous Catalysis
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Contents
1 Introduction to Thermodynamic EnergyDependent and Mechanical TimeDependent Processes What Are They and How Are They Manifested in C... | 1 |
2 Heterogeneous Homogeneous and Enzymatic Catalysis A Shared Terminology and Conceptual Platform The Alternative of TimeDependence in Ca... | 37 |
3 A Conceptual Description of EnergyDependent Thermodynamic and TimeDependent Mechanical Processes in Chemistry and Catalysis | 55 |
4 TimeDependence in Heterogeneous Catalysis Sabatiers Principle Describes Two Independent Catalytic Realms TimeDependent Mechanical Catalysi... | 77 |
5 TimeDependence in Homogeneous Catalysis 1 Many Enzymes Display the Hallmarks of TimeDependent Mechanical Catalysis Nonbiological Hom... | 97 |
6 TimeDependence in Homogeneous Catalysis 2 The General Actions of TimeDependent Mechanical and EnergyDependent Thermodynamic Catalysts | 137 |
7 Unifying the Many Theories of Enzymatic Catalysis Theories of Enzymatic Catalysis Fall into Two Camps EnergyDependent Thermodynamic and ... | 161 |
8 Synergy in Heterogeneous Homogeneous and Enzymatic Catalysis The Ideal Catalyst | 181 |
10 The Rational Design of TimeDependent Mechanical Homogeneous Catalysts A Literature Survey of Multicentered Homogeneous Catalysis | 219 |
11 TimeDependent Mechanical Nonbiological Catalysis 1 A Fully Functional Mimic of the WaterOxidizing Center WOC in Photosystem II PSII | 267 |
12 TimeDependent Mechanical Nonbiological Catalysis 2 Highly Efficient Biomimetic HydrogenGenerating Electrocatalysts | 297 |
13 TimeDependent Mechanical Nonbiological Catalysis 3 A Readily Prepared Convergent OxygenReduction Electrocatalyst | 319 |
Appendix A Why Is Saturation Not Observed in Catalysts that Display Conventional Kinetics? | 337 |
Appendix B Graphical Illustration of the Processes Involved in the Saturation of Molecular Catalysts | 341 |
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9 A Conceptual Unification of Heterogeneous Homogeneous and Enzymatic Catalysis | 209 |
Other editions - View all
Mechanical Catalysis: Methods of Enzymatic, Homogeneous, and Heterogeneous ... Gerhard Swiegers No preview available - 2008 |
Mechanical Catalysis: Methods of Enzymatic, Homogeneous, and Heterogeneous ... Gerhard Swiegers No preview available - 2008 |
Common terms and phrases
achieved activated reactants activation energy active site atoms binding and activating biomimetic bound reactants catalyst-mediated collision frequency catalyst-reactant binding catalytic action catalytic effect catalytic groups catalytic process catalytic rate Chapter Chem chemical chemistry collision frequency combinatorial complementary complex conformational flexing coordinated cubane dependent depicted in Figure described dioxygen display dominoes dynamic efficiency electrochemical electrode employed energy barrier energy-dependent catalysts enzymatic catalysis enzymes Equation equilibrium example ferrocene functionally convergent heterogeneous catalysis homogeneous catalysts hydrogen increase intermediate involves ligand mechanical metal molecules monomeric monomers multicentered catalysts Nafion nonbiological homogeneous catalysts occur optimum overall rate pathways photocurrent physical polymer polypyrrole porphyrin potential properties proton pyrrole reactant binding reactant concentration reaction rate reactive reduction references therein release saturation Schematic Scheme single-centered spatial arrangement species step structure substrate Swiegers synchronized synergies thereby thermodynamic time-dependent catalysts time-dependent processes transition state formation transition state theory typically uncatalyzed volcano plot water oxidation