A Quantitative Study of a One-electron Photoöxidation in a Rigid Medium: The Photoöxidation of Tetramethyl-p-phenylenediamine in 3-methylpentane at 770K. |
Common terms and phrases
3-methyl A. C. Albrecht absolute intensity absorbed by TMPD absorption band absorption spectrum actinometer AH-6 lamp anisotropy blank and sample calculated Chem concentration of WB constant correlation coefficients density of WB determined dewar donor electron affinity electronically excited equation escence esculin exciting light exit slit ficient filter fluid solution fluorescence and phosphorescence G. N. Lewis given wave length high energy illumination incident light intensity indirect path integrating screen irradiation isopentane isopropyl alcohol lengths of excitation liquid nitrogen measurements metastable molar extinction coefficient molecular axis molecules monochromator exit mp intervals observed obtain oxidation path length pentane phorescence photo-product photochemical unit photochemistry photoöxidation quantum phototube quantum yields r₂ reactant relative fluorescence rigid glass rigid media search unit singlet solution solvent spectra spectrum of TMPD TMPD in 3-methylpentane triplet tube tunneling various wave lengths vibrational mode wave length dependence WB optical density yields of fluorescence yields of photoöxidation