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absolute intensity absorbed by TMPD absorption band absorption spectrum actinometer AH-6 lamp anisotropy blank and sample calculated concentration of WB correlation coefficients density of WB determined dewar donor electron affinity equation esculin exciting light exoitation filter fluid solution fluorescence and phosphorescence given wave length high energy incident light intensity Indirect path integrating screen irradiation isopentane isopropyl alcohol lengths of excitation light absorbed liquid nitrogen metastable molar extinction coefficient molecules observed obtain oxidation path length pentane photo corrected photo-product photochemical reactions photochemical unit photochemistry photometer photooxidation of TMPD photooxidation quantum yields phototube pnoto pyrex relative fluorescence rigid glass rigid media rigid solvent room temperature search unit singlet solution spectra spectrum of TMPD TMPD absorption TMPD and WB TMPD In 3-methylpentane triplet tube tunneling various wave lengths VB optical densities vibrational mode wave length dependence WB optical yields of photooxidation