Introduction to chemical engineering thermodynamics
"Introduction to Chemical Engineering Thermodynamics, 6/e," presents comprehensive coverage of the subject of thermodynamics from a chemical engineering viewpoint. The text provides a thorough exposition of the principles of thermodynamics and details their application to chemical processes. The chapters are written in a clear, logically organized manner, and contain an abundance of realistic problems, examples, and illustrations to help students understand complex concepts. New ideas, terms, and symbols constantly challenge the readers to think and encourage them to apply this fundamental body of knowledge to the solution of practical problems. The comprehensive nature of this book makes it a useful reference both in graduate courses and for professional practice. The sixth edition continues to be an excellent tool for teaching the subject of chemical engineering thermodynamics to undergraduate students.
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The First Law and Other Basic Concepts
Volumetric Properties of Pure Fluids
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activity coefficients adiabatic applied assumed azeotrope Calculate Carnot cycle chemical CM CM CM CN CN CN composition compression compressor condenser const constant pressure cooling correlation curve cycle cylinder determined diagram efficiency enthalpy entropy entropy change equation equilibrium ethylene Example expansion expression flow fluid fugacity function gases Gibbs free energy given by Eq heat capacity heat engine heat of reaction heat transfer Henry's law ideal gas initial integration internal energy irreversible isothermal l(atm l(mol liquid phase mass methane mixture molar volume mole fraction mole percent nitrogen nozzle obtained OOOOO OOOOO operation piston pound mass pump quantity Raoult's law ratio reactants reaction coordinate refrigeration represented result saturated liquid shown in Fig standard heat steam surroundings tank temperature and pressure thermodynamic properties turbine values vapor phase variables velocity virial coefficients virial equation zero