Introduction to Magnetochemistry |
Contents
Free Atoms and Ions | 9 |
Transition Metal Complexes | 32 |
Van Vlecks formula for susceptibility | 45 |
Copyright | |
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angular momentum vector antiferromagnetism applied arise atomic susceptibility behaviour binuclear co-ordination compared to kT component compounds corresponding crystal field theory cubic fields Curie law Curie-Weiss law d³ configuration diamagnetic dilute doublet electronic configuration equation exp kT experimental F terms ferromagnetic free ion ground term higher Hund's inner orbital interaction kT kT ligand field lowest magnetic field magnetic moment magnitude measurements molar susceptibility molecules multiplet widths netic nitrogen obtained occur octahedral complexes octahedral field orbital angular momentum orbital contribution order Zeeman effect paramagnetic paramagnetic ions possible precession room temperature row transition metal sample second order Zeeman singlet solutions sp³d2 specimen spin and orbital spin-free spin-only value spin-orbit coupling spin-paired stereochemistry strong field substance T₂ temperature dependence tetrahedral tetrahedral field tion transition metal transition metal ions triplet tube unpaired electrons valence bond theory Zeeman effect ΧΑ
