Enantiomers Racemates and Resolutions
Analyzes in detail the properties of enantiomers (fusion behavior, solubility, crystallization, distillation, and sublimination), enantiomer mixtures, and racemates. Surveys theory and practice of resolutions, considering classical and chromatographic resolutions and those by direct crystallization. Discusses the monitoring of resolutions through appropriate enantiometric purity determinations.
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RACEMATES AND THEIR ENANTIOMER CONSTITUENTS
Relationships Between Arrays of Enantiomers and
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Abstr acid Acta addition alcohols allows American Chemical Society amine analysis applicable base binary Bull calculated carried Chem Chim chiral chromatography cinchonine common complex composition concentration conglomerate consists containing corresponding crystalline crystals curve derivatives described determination diastereomeric salts diastereomers enantiomeric purity enantiomers equal equation equilibrium esters ethanol eutectic examine example existence experimental fact Figure formation function given gives heating illustrated isolated Jacques latter leads less limited liquid measurements melting point method mixture mole molecules observed obtained optically active organic particular phase diagram possible present properties pure pure enantiomer quantity racemic compound relatively remains represents Reproduced by permission resolution resolving agent rotation sample separation solid solutions solubility solvated solvent space groups specific structure studied substance symmetry Table takes temperature transformation yield