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Inclusion Complex Formation
Catalyses by Cyclodextrins Leading to Practical Usages
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a-CD a-cyclo Abstr acceleration by cyclodextrin acyl-cyclodextrin acylation alkaline alkoxide ion Amer American Chemical Society anions anisole apolar aqueous solution Bender benzene benzoic acid binding Bioorg Breslow carbonyl carbonyl carbon atom catalyses by cyclodextrins catalysis catalytic rate constant Chem Chemistry chymotrypsin cleavages of phenyl concentration conformational covalent catalyses covalent intermediate Cramer cyclic cyclo cyclodex cyclodextrin cavity cyclodextrin molecule cyclodextrin-accelerated cyclodextrin-catalyzed deacylation step decarboxylation dextrin dimethyl sulfoxide dissociation constant enantiomer enthalpy entropy enzyme exhibited fold glucose guest compounds hydrogen bonds hydrolyses of phenyl hydrolysis hydrophobic inclusion complex formation interactions intramolecular Japan Kokai Patent kcal/mole Kokai Kokai Patent 75 Komiyama Kuge larger m-nitrophenyl acetate methyl microsolvent effect molecular native a-cyclodextrin Noncovalent nucleophilic attack organophosphates p-nitrophenol Pharm phenyl esters plex primary hydroxyl groups protons rate constant reaction reactive ring Saenger Schardinger Scheme secondary hydroxyl groups showed sodium solvent structure substrate Table tion trin Waals water molecules whereas