Part I. Nuclear magnetic resonance studies of anisotropic molecular rotational diffusion in liquids: Part II. A study on the application of ion-cyclotron magnetic resonance to problems in prebiotic synthesis |
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Contents
THEORETICAL | 7 |
B The Rotational Diffusion Constants | 17 |
Nuclear Spin Relaxation | 26 |
16 other sections not shown
Common terms and phrases
amino acids angle angular momentum angular velocity anisotropic asymmetric-top axis system becomes benzene bond calculated Chem chemical shift chlorine-35 chloroform coefficients collision complex correlation function coupling constants d3is density deuterochloroform deuteron deuteron relaxation diagonalizes the diffusion dielectric relaxation diffusion axes diffusion constants diffusion equation diffusional dimethylformamide dipole dipole-dipole double resonance eigenfunctions ensemble equimolar exponential field gradient formyl deuteron gas phase given in Figure Hamiltonian initial intermolecular interactions internal rotation linewidth liquid magnetic matrices measured mechanism methyl deuterons methyl groups mixture molecular coordinate system molecular reorientation molecule neat nucleus obtained orientation overall molecular rotation perpendicular Phys planar asymmetric rotor plane principal diffusion proton pulse quadrupolar nuclei quadrupole quadrupole coupling constants reaction rotational diffusion constants rotational diffusion tensor rotational motion solution space-fixed spectral spectrometer symmetry axis system that diagonalizes values xx yy