Advances in Strained and Interesting Organic Molecules, Volume 8
The eighth volume of this series comprises six chapters and describes a variety of interesting strained and not so strained molecules and their use - or abuse - in the widest sense. This volume contains a position summary of planar carbon networks, the field of strained allenesis addressed by considering the five- to- nine-membered ring derivatives and this is followed by an introduction to the nature of carbene geometry and the use of ESR spectroscopy in deducing carbene structure. The use of strained molecules in the synthesis of important new compounds of a natural and non-natural nature is a main theme in the volume. Other areas that are discussed are strained carbohydrates, stereocontrolled access to natural products and polymer systems as well as a much sought after contribution to the series on small-ring nitrogen heterocycles.
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CHAPTER 2 RECENT DEVELOPMENTS IN STRAINED CYCLIC ALLENES
CHAPTER 3 STRAIN AND STRUCTURE OF STERICALLY CONGESTED TRIPLET CARBENES
CHAPTER 5 EXPLOITING THE STRAIN IN 221 BICYCLIC SYSTEMS IN POLYMER AND SYNTHETIC ORGANIC CHEMISTRY
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1-leimgartner 2H-azirines 3DPC Acta aldehyde alkene alkylidene alkyne allyl Angew anhydride aromatic azide aziridines azirine Balci benzene bond angle carbene carbene center carbohydrates carbon atom catalyst Chem chemistry Chim chiral complex compounds conﬁguration cyclic allenes cyclization cycloaddition cyclopentane cyclopropane Danishefsky delocalization derivatives diastereomer diastereoselectivity dimerization Diphenylcarbenes double bond DPIBF electrons energy Engl epoxide ester Et3N ﬁeld ﬁrst formation geometry glycal graphyne Hassner hemiacetals heterocycles initiator intermediate intramolecular isomer isomeric isoxazoles kcal/mol lactone Lewis acid linear macrocycle matrix methyl groups mixture molecular molecule monomers nitrile nitrile ylide nitrogen norbomene nucleophilic observed oleﬁn optically active orbital oxidation Ph Ph phenyl photolysis polymerization polymers prepared react reaction reactivity Reagents rearrangement regioselectivity ring expansion ring opening ring system ROMP Scheme 16 shown in Scheme signiﬁcant speciﬁc stable steric strained structure substituents synthesis synthetic temperature Tetrahedron Lett triplet carbenes undergo yield ZFS parameters