Large molecules in carbon vapor
Kenneth S. Pitzer, Enrico Clementi, Lawrence Radiation Laboratory, University of California, Berkeley. Lawrence Radiation Laboratory
Lawrence Radiation Laboratory, 1959 - Science - 35 pages
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adjusted to triple AH of formation allene and ethylene band Basset bond distance Brewer cal/deg mole carbon chains carbon molecules Chem Chupka Compressional energies conjugation energy delocalized dimensional metals Doehaerd effusion experiments electron affinity Electron orbital energy electronegativity energy function increment energy levels enthalpy entropy equilibrium with graphite estimated evaporation coefficients field atomic orbitals free energy function Goldfinger heat of formation heat of fusion heat of sublimation heat of vaporization Honig ij ij Increment per carbon interior atoms interior carbon atom kcal kcal/gm atom kcal/mole L-F energies L-F method larger molecules Lawrence Radiation Laboratory liquid carbon Lofthus long chain long linear molecular orbital energies molecular orbital theory MOLECULES IN CARBON Mulliken number of carbon observed odd species Phys predict respectively ring molecules secular equation Slater orbitals sticking coefficient Table Thorn and Winslow triple point pressure uncertainty vapor pressure Waeibroeck yields zero overlap integral