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Useful Intermediates in Organic
4A Caged Pyramidalized Alkenes
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acid active addition afford alcohols American Chemical Society Angew angle anti reflex approach axial benzene bond bridge bromine cage calculations carbon carbonyl cation Chem Chemical chemistry co-workers Commun complex compounds conformation converted corresponding cubane cubyl cyclization cyclohexane cyclophanes derivatives diene Eaton energy example Figure followed formation formed functional gave give H H H hydrocarbon interaction interesting intermediate intramolecular involved irradiation isomer isomerization kcal mol ketones lead macrocyclic Marchand mechanism Mehta method mixture molecular molecules natural observed obtained occurs olefin organic oxidation Paquette Ph Ph possible prepared presence radical reaction reactivity rearrangement recently reduction References reflex effect relative reported respectively ring Scheme shift shown skeleton stable strained structure studies substituted synthesis Table Tetrahedron Lett tion trans treatment various yield