Nuclear Magnetic Resonance Studies of Solvation in Methanol |
Common terms and phrases
average Ca++ calculated CH₂OH CH3OH Chem chemical shifts Co++ compressibility coordinated environments coordinated methanol coordinated water coordination sphere cps separation determine the coordination determining coordination numbers determining solvation numbers diamagnetic entropy equilibrium quotient Figure free solvent methanol gram moles hydration number hydration sphere hydrogen bond hydroxyl proton absorp hydroxyl proton peaks Increasing Magnetic Field ions isotopic dilution method lower magnetic field magnesium perchlorate Magnetic Field Fig Mg++ mole H₂O mole of salt moles CH₂OH/0.84 mole moles CH3OH/1.31 moles moles H20 moles of methanol moles of water moles water NMR Proton Spectrum nuclear magnetic resonance number of water Numbers of Mg OH CH3 Phys Pr+++ primary solvation number proton absorption proton NMR spectra Sol'n solvation sphere solvent molecules Spectrophotometric spectrum at 85 Spectrum of Mg spectrum of solution Stanford University Stoke's law structure Swinehart Taube tion trolyte Ulich Varian Associates viscosity volume water molecules water per mole Zn++