The Surface Chemistry of SoilsDescribes the surface phenomena in soils, both experiment and theory, from the point of view of modern coordinational chemistry. The topics covered include surface area and change, the structure of absorbed water, the points of zero change, electrokinetic phenomena, adsorption of inorganic and organic solutes, computer models of adsorption, a nd colloidal aspects of surface chemistry in soils |
Contents
THE REACTIVE SOLID SURFACES IN SOILS | 1 |
CHEMICAL MODELS OF SURFACE COMPLEXATION | 5 |
THE STRUCTURE OF WATER NEAR CLAY MINERAL SURFACES | 51 |
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acid activity adsorbed adsorption anion applied aqueous solution assumption bonds bulk calculated cation Chem chemical Clay Minerals Colloid concentration condition constant containing decreases depends described determined difference discussed ditrigonal cavities effect electric electrokinetic electrolyte electron equal equation equilibrium evidence example exchange exists expected experimental experiments expression follows force formation functional groups given goethite hydrate hydroxyl groups increases indicated inner-sphere interactions interface interlayer involved ionic ions kaolinite layer Lewis liquid water measured mechanism metal cations methods mobility molecular moles montmorillonite negative neutron organic outer-sphere oxide parameters particle phase phyllosilicate plane positive possible potential present properties proton reaction refers region relative result sheet siloxane surface smectite soil clay Soil Sci soil solution solid solvation specific structure studies substitution surface area surface charge surface complexes suspension Table tetrahedral theory thermodynamic tion unit vermiculite water molecules zero