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2p orbitals 3-decalol 77 electron system absorption band absorption intensity angle of twist atomic orbitals axis become allowed berekend bond moments C=O group calculated carbonyl chapter chromophoric system circular dichroism CM CM CM coefficients component compounds configuration conjugated system constant g-factor curve cyclohexane diacetic acid diene system direction electric and magnetic electric transition ellipticity estimated experimental Figure g-factor geometry H-atoms helix Hiickel hybridization interaction isooctane J.Chem.Phys Kauzmann ketones Klyne Kramers-Kronig Kramers-Kronig relations lefthanded Leiden linear combinations longest wavelength magnetic transition moments measurements molar rotation molecular frame molecular orbitals molecule one-electron optical rotatory dispersion optical rotatory power optically active order of magnitude oscillator strength oxygen parallel perturbation planar plane polarizabilities polarized light Pople refractive index result rotation at 350 sample scalar product solvent isooctane spectrum symmetry theoretical tion trans 3-decalone trans cyclohexane transitional bond orders U.V. absorption ultra-violet vibrational vibronic transition wave functions wavelength werd zero