## Hyperfine and Spin-rotation Interactions in the Hydrogen Molecule-ion |

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### Contents

Solution of Nonrelativistic Electronic | 15 |

Solution of Nuclear Schrodinger | 24 |

The Effective Spectroscopic Hamiltonian | 42 |

6 other sections not shown

### Common terms and phrases

accuracy angular momentum Appendix atomic units Basis Set bH CH Bishop and Wetmore Born-Oppenheimer approximation calculation Chapter Chem CM CM continued K bH convergence Cooley-Cashion curve diagonal eigenfunctions eigenvalues eigenvectors electric field electron spin electronic and nuclear electronic energy elliptical coordinates evaluation expectation value experimental Figure first-order function of internuclear g factor H2 and HD hamiltonian hyperfine components hyperfine constants hyperfine energy levels hyperfine interactions hyperfine levels hyperfine structure infrared interaction coefficients interaction functions internuclear separation interpolation lattice Lett matrix elements Menasian molecular rotation momenta Morse potential nonrelativistic electronic nuclei one-electron diatomic molecule Pauli equation perturbation Phys Poisson sum formula quantum numbers reference diagram relative intensities representation ROGER DEAN rovibrational transitions simple product basis simulated solution spectra spectroscopic constants spherical spin-rotation interaction surface unit cell Table VI.1 theoretical transition frequencies transition intensity variation vector vibrational-rotational VM(R wave function Wigner-Eckart theorem