Vibrational Energy Transfer Processes in the HF-HCl, HF-HBr, HF-HI and HF-DF Systems |
Common terms and phrases
104 sec ¹torr¹ ¹torr-1 350 K respectively 50 torr a₁ absorption cell Argon mixtures b₂ C. B. Moore capacitance manometer Chem CHEMICAL LASER Chen and Moore choked flow cm¯¹ cold trap data traces deactivation rates detailed balance relation detector distilled dry ice emission energy transfer processes exponential decay flow fluores fluorescence decay rates FLUORESCENCE INTENSITY Gas handling H₂ HF and DF HF and HX HF deactivation HF fluorescence decay HF or HX HF-DF mixture HF-HBr HF-HCl HF-HX hydrogen hydrogen bonding InSb Laser induced fluorescence laser pulse line strength matrix elements microns mixture at 350°K molecules Observed HF fluorescence P-branch partial pressures Phys plots Pump R. R. Stephens rate constants rates for HF-HI reduced mole fraction relaxation rate rotational rotational constant sec ¹torr shock tube shown in Figure single exponential decay species T. A. Cool thermocouple transitions V-V rate values waveform eductor XHBr