Chemical Kinetics: The Study of Reaction Rates in Solution
Chemical Kinetics The Study of Reaction Rates in Solution Kenneth A. Connors This chemical kinetics book blends physical theory, phenomenology and empiricism to provide a guide to the experimental practice and interpretation of reaction kinetics in solution. It is suitable for courses in chemical kinetics at the graduate and advanced undergraduate levels. This book will appeal to students in physical organic chemistry, physical inorganic chemistry, biophysical chemistry, biochemistry, pharmaceutical chemistry and water chemistry-all fields concerned with the rates of chemical reactions in the solution phase.
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absorption acetate acid acid-base alcohol applied approximation Arrhenius Arrhenius equation base bond calculated catalysis Chapter Chem Chemical Kinetics Chemistry complex concentration correlation curve defined dependence described differential rate equations electronic elementary reaction equilibrium constant ester estimates ethyl example experimental factor Figure free energy frequency function gives Hammett hydrolysis initial interaction intermediate ionization isotope effect Jencks kinetic scheme LFER linear magnetic measure mechanism method molar molecular molecules nucleophilic nucleus observed obtained parameters Phys plot polarity potential energy surface proton quantity rate constant rate equation ratio reactant reaction coordinate reaction rate reaction series reactivity reagent relationship relaxation resonance result second-order Section slope SN2 reactions solution solvation solvent effects solvolysis steady-state approximation steric steric effect substituent substituent constant substrate Table temperature theory transition transition state theory values variables York zero