Nonadiabatic Bound States of Isolated Molecules |
Common terms and phrases
adiabatic adiabatic approximation adiabatic potential adiabatic surfaces assignment atomic band system basis functions benzene benzene's Born-Oppenheimer approximation calculations cation Chapter Chem cm-ยน cm-1 region configuration conical intersection correlation decay degeneracy degenerate derived diabatic basis diabatic formulation diagonal dye laser electronic basis electronic term energy levels equation experimental ground hamiltonian He(Q intensity interaction internuclear ion core ionic ionization potential Jahn-Teller effect Jahn-Teller modes jet-cooled limit linear lowest matrix elements molecular orbital molecules multiphoton nonadiabatic effects nonlinear nuclear motion nuclei observed obtained off-diagonal one-photon origin parameters perturbation photon Phys polarization potential energy surfaces potential surfaces predicted problem quantum defects quantum number Renner Rydberg electron Rydberg orbital Scharf selection rules sequence band spectra spectroscopy splitting symmetry coordinates term value three-photon tion toluene totally symmetric transitions triazine two-photon absorption Two-photon resonant two-photon spectrum ultraviolet valence vibrational vibronic coupling vibronic levels vibronic structure wavefunctions Whetten