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A Diabatic Formulation
Quantum Mechanical Adiabatic Approximation
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adiabatic approximation adiabatic potential adiabatic surfaces assignment atomic band system bandwidth basis functions benzene's calculations cation Chapter Chem cm-1 region configuration conical intersection correlation cyclohexane decay degeneracy degenerate derived diabatic basis diabatic formulation diagonal dye laser E.R. Grant electronic basis electronic terms electronic wavefunctions energy levels equation experimental Figure frequency ground hamiltonian He(Q hot bands intensity interaction internuclear ion core ionic ionization potential Jahn-Teller effect Jahn-Teller modes jet-cooled limit lowest major matrix elements molecular orbital molecules multiphoton nonadiabatic effects nonlinear observed obtained off-diagonal one-photon origin parameters perturbation photoelectron photon Phys polarization potential energy surfaces potential surfaces predicted problem pseudorotation quadratic coupling quantum defects quantum mechanical quantum number Renner resonances Rydberg electron Rydberg orbital Rydberg series Scharf selection rules sequence band spectra spectroscopy splitting symmetry symmetry coordinates tion toluene totally symmetric transition triazine two-photon absorption two-photon spectrum ultraviolet valence vibrational vibronic coupling vibronic structure vibronic transitions wavefunctions