Electrochemical Systems |
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Introduction | 1 |
Part A Thermodynamics of Electrochemical Cells | 27 |
Cell with solution of uniform concentration | 39 |
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activity coefficients anodic applied binary electrolyte boundary conditions bulk solution c₁ calculated cathodic cation cell potential charge density chemical potential chloride cm²/sec composition concentration overpotential concentration profiles concentration variations constant current density current distribution depends difference diffusion coefficient diffusion layer dilute solutions dimensionless disk electrode dissociation double layer elec electric field electric potential electrochemical potential electrochemical systems Electrochemistry electrode reaction electrode surface electrolyte electrolytic solution electroneutrality equilibrium exchange current density expressed Figure flow fluid flux free convection gradient H₂O interface ions John Newman laminar Laplace's equation limiting current mass transfer mass-transfer measured metal migration molality molar number of species ohmic potential drop phase pressure problem Pt(s reactant reference electrode region rotating disk Schmidt number single electrolyte solvent standard cell potential sulfate sulfuric acid supporting electrolyte surface overpotential temperature theory thermodynamic tion transference number transport properties turbulent zero