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Introduction 1 Thermodynamics electrode kinetics and transport processes
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activity coefficients anodic applied binary electrolyte boundary conditions bulk solution calculated calomel electrode cathodic cation cell potential charge density chemical potential chloride cm2/sec coefficient of species composition concentration overpotential concentration profiles concentration variations constant copper current density current distribution Debye depends diffusion coefficient diffusion layer dilute solutions dimensionless disk electrode dissociation double layer elec electric field electric potential electrochemical potential electrochemical systems Electrochemistry electrode reaction electrode surface electrolyte electrolytic solution electroneutrality equilibrium exchange current density expressed Faraday's constant Figure flow fluid flux gradient interface ionic species ions laminar Laplace's equation limiting current liquid junction liquid-junction potentials mass transfer mass-transfer measured metal migration molality molar number of species ohmic potential drop phase pressure problem reactant reference electrode region rotating disk Schmidt number single electrolyte solvent standard cell potential sulfate sulfuric acid supporting electrolyte surface overpotential temperature theory thermodynamic tion transference number transport properties turbulent zero