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Preface to the First Edition vii
The Contribution from Statistical Mechanics
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acid concentration acid-water mixtures acidity constant acidity function activity coefficient alkyl anion approximation aqueous solution atom azide base benzene benzoic acids bromide butyl carbon carboxylic catalysis cation Chem chemical chemistry chloride compound conjugate acid considerable correlation decrease derivatives deviation dielectric constant difference dilute solution dimethylsulfoxide dissociation electrolyte energy enthalpy entropy equation equilibrium constant ester ethyl experimental first-order formation free-energy relationships hydrogen bonding hydrolysis increase independent interaction intermediate involved ion pair ionic strength ionization kinetics linear lithium measure mechanism medium meta methanol mobile equilibrium molal mole nitromethane oxygen percent perchlorate phenol Phys plot proton pyridine quantity racemization rate-determining ratio reactant reaction product reaction rate reacts relation relationship salt effect slope sodium solvation solvent solvent molecules solvolysis specific rate standard potential structure substance substituents sulfuric acid Taft temperature theory transition transition-state Winstein zero