Physical Organic Chemistry: Reaction Rates, Equilibria, and Mechanisms |
Contents
Preface to the First Edition vii | 1 |
The Contribution from Statistical Mechanics | 37 |
Chapter 4 | 53 |
Copyright | |
10 other sections not shown
Common terms and phrases
acid concentration acid-water mixtures acidity constant acidity function activity coefficient alkyl anion aqueous solution atom base benzene benzoic acids bromide Brønsted carbon carboxylic catalysis cation Chem chemical chemistry chloride compound conjugate acid considerable correlation decrease derivatives deviation dielectric constant difference dilute dimethylsulfoxide electrolyte energy enthalpy entropy equation equilibrium constant ester ethyl experimental formation free-energy relationships hydrogen bonding hydrolysis increase independent interaction intermediate involved ion pair ionic strength ionization k₁ k₂ kcal kinetics L. P. Hammett linear lithium measure mechanism medium meta methanol mobile equilibrium mole nitromethane percent perchlorate phenol Phys plot proton pyridine quantity racemization ratio reactant reaction product reacts relationship RTln salt effect slope sodium solvation solvent solvolysis specific rate standard potential structure substance substituents sulfuric acid t-butyl Taft temperature theory transition transition-state Winstein zero ат